General Information
Ultraviolet
curing is a photochemical process in which an abundant amount
of UV energy is produced by a mercury discharge lamp and focused
at monomers through cross linking or polymerization. The sensitizer
present in the monomer absorbs UV radiation at a rapid rate and
initials the reaction in the monomer, producing a hard and dry
surface. The rate or speed of the curing process depends
on the following:
(A)
Chemical Compound - Each monomer will cure at a different rate,
depending upon the composition and the amounts of sensitizer, pigment
and the chemical additives.
(B)
Thickness of Coating - The thickness of a specific coating is not
directly proportional to exposure time. The amount of UV
energy inside a layer of coating decreases exponentially with depth. If
70% if the UV energy is absorbed in the top .001" if coating, then
70% of the remainder or 7% of the initial amount will be absorbed
into the second .001" if coating. Thus, a two fold increase
in thickness requires a ten fold increase in UV intensity.
(C)
Amount of UV per Unit Surface - Normally, the curing speed will
increase with the amount of UV energy per unit surface at a non-linear
rate. If a 200 watt per inch mercury lamp was increased to
400 watt, the curing speed could increase ten fold. In addition,
special Superior metal halide lamps can trigger the receptor at
an even faster rate with a standard 200 watt per inch lamp. The
charts in Figure 1 dictate
the flexible control that Superior technology has developed over
the years. We can pinpoint the UV energy produced by our
curing lamps to your exact specifications.
The sensitizer
should absorb UV in the range which is not absorbed by the monomer
or pigment. The wavelength produced by a Superior medium pressure
mercury lamp or Superior metal halide lamp should coincide with the
wavelength absorbed by the sensitizer. The continuous light spectrum
produced by these lamps in the 200 to 440 nanometer range propels
technology to a plateau of efficiency.
Radiation
emitted from our mercury lamp depends on many factors. In
a gas discharge lamp, the output is a function of the atomic structure
of the gas molecules, their temperature, pressure of the gas vapor,
and quality of materials used in the basic construction. Superior
lamps utilize only the finest raw materials available. Second
best will not do.
If
your application requires the absence of ozone gases, which is
a by-product of an ultraviolet producing lamp, our engineering
department can effectively respond with a special grade of quartz
that prevents the 254 nanometer line from reaching oxygen in the
atmosphere. Please bear in mind that all effective lines
below 254 nanometers are blocked which might be required to start
your reaction. Figure 2 shows
the basic area of interest for industrial curing.
(D)
The UV Spectrum - Once the basic concept of radiation has been
understood, how ultraviolet radiation fits into the scheme of things,
and what UV Curing contains, then, one can easily understand the
advantages and disadvantages of various light sources. Standard
Superior curing lamps display the following characteristic in Figure
3.
The
far ultraviolet lies between 200mn and 300mn and is classified
as Germicidal or UV-C. The middle ultraviolet lies between
280nm and 320nm is called Erythema (suntan) or UV-B. The
near ultraviolet lies between 320nm and 400nm and is commonly called
Black Light (long ultraviolet) or UV-A.
The
Superior medium pressure lamp builds vapor pressure as the power
and temperature start to increase. As shown below in Figure
4, as the power input increases, so does the efficiency (ratio
of total radiation to power input. From 100 watt per inch
to 300 watt per inch the efficiency is increased by 12%)
TOTAL
RADIATION EFFICIENCY |
| Input Power (watt/inch) |
Efficiency R/P % |
| 40 |
27 |
| 50 |
36 |
| 100 |
54 |
| 200 |
63 |
| 300 |
66 |
| 400 |
67.5 |
| Figure
4 |
This efficiency further evolves from the
highly skilled technicians that receive years of critical training
and their adaptability to construct flawless linear lamps. Our Superior
400 watt per inch lamp will more than double the cure rate when compared
to two lamps running at 200 watt per inch each.
The spectral output does not shift as
the lamp power is increased from 100 to 200 to 300 watts per inch.
There are a multitude of medium pressure mercury lamps varying in
shape, size, diameter, length and power output. Please note that
a Superior lamp operating on a properly designed stabilized ballast
has a power conversion from line input to lamp output of 92%. The
biggest advantages of the Superior line of curing lamps are low cost,
an inventory stocked with various standard lengths of 1.5 inches
to 180 inches, and the reputation that goes with the name.
(E)
Advantages - The Superior line of UV curing is paramount to conventional
heat curing in many areas.
(1.)
A drastic reduction in "air pollution" becomes possible with the
monomer system of excitation. No solvent need be evaporated and
expelled into the atmosphere
(2.)
The fast and rapid curing rate of Superior standard lamps is known
worldwide. Add the correct mix of exotic materials at the same
power level and the future starts to unfold. Remember. the efficiency
exceeds 90%, and that means saved dollars every second of a work
day.
(3.)
Huge savings in plant space, labor costs, and the highest quality
in improved appearance cannot be overlooked.
|